Simultaneous Spectrophotometric Determination of Vanadium(V) and Iron(III) in Micellar Medium by H-Point Standard Addition Method
نویسندگان
چکیده
H-Point Standard Addition Method (HPSAM) was applied for the simultaneous determination of V(V) and Fe(III). The method is based on the complex formation of V(V) and Fe(III) with chromazurol S (CAS) in acidic media and in the presence of cetyltrimethylammonium bromide (CTAB) as a micellizing agent. Acidic media and the presence of a micellar system improve selectivity and sensitivity. Fe (III) and V (V) could be determined simultaneously in the range of 0.1-2 and 0.2-2 μg / mL, respectively, and with the ratio 1:20 to 10:1 Fe(III)/V(V) in the mixed samples. The proposed method was successfully applied to the simultaneous determination of Fe(III) and V(V) in tap, river, saliva and plasma samples.
منابع مشابه
Simultaneous Spectrophotometric Determination of Vanadium(V) and Iron(III) in Micellar Medium by H-Point Standard Addition Method
H-Point Standard Addition Method (HPSAM) was applied for the simultaneous determination of V(V) and Fe(III). The method is based on the complex formation of V(V) and Fe(III) with chromazurol S (CAS) in acidic media and in the presence of cetyltrimethylammonium bromide (CTAB) as a micellizing agent. Acidic media and the presence of a micellar system improve selectivity and sensitivity. Fe (I...
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